the APPENDIX 2 To influence of concentration of reagents, components of catalytic system and temperatures for the speed gidrokarbometokislirovanija tetrahydrobenzene.
Table 1. To influence Pd (PPh3) 2Cl2и temperatures for the speed gidrokarbometoksilirovanija tetrahydrobenzene.
РСО=2,00 MPa; concentration, a mole/l: [C6H10] =0,10, [CH3OH] =0,45,
[PPh3] =4,0∙10^2, [TsOH] =3,0∙1 θ ' 2
T, minute | [3 φ.] ∙ 102, Mole/l | T, minute | [3 φ.] ∙ 102, Mole/l | T, minute | [3 φ.] ∙ 102, Mole/l |
1 | 2 | 3 | 4 | 5 | 6 |
Т=378К
[Pd (PPh3) 2Cl2] = 0 [Pd (PPh3) 2Cl2] = 5,0∙10-4M [Pd (PPh3) 2Cl2] =1,0∙10-3M
5 | 0,11 | 5 | 0,08 | 5 | 0,15 |
10 | 0,12 | 10 | 0,11 | 10 | 0,10 |
15 | 0,08 | 15 | 0,13 | 15 | 0,15 |
25 | 0,08 | 25 | 0,27 | 25 | 0,26 |
35 | 0,06 | 35 | 0,61 | 35 | 0,42 |
50 | 0,16 | 50 | 0,80 | 50 | 0,72 |
70 | 0,31 | 70 | 1,23 | 70 | 1,10 |
90 | 0,29 | 90 | 1,70 | 90 | 1,57 |
115 | 0,34 | 115 | 1,93 | 115 | 2,05 |
150 | 0,44 | 145 | 2,68 | 145 | 2,58 |
185 | 0,57 | 185 | 2,90 | 185 | 3,06 |
230 | 0,70 | 230 | 3,93 | 230 | 3,87 |
280 | 0,78 | 280 | 4,77 | 280 | 4,78 |
Т=378К
[Pd (PPh3) 2Cl2] = 6,0∙10^3 M [Pd (PPh3) 2Cl2] = 8,0∙10-3 M [Pd (PPh3) 2Cl2] = 1,0∙10^2 M
5 | 0,08 | 5 | 0,12 | 5 | 0,09 |
10 | 0,16 | 10 | 0,28 | 10 | 0,37 |
20 | 0,62 | 15 | 0,65 | 15 | 0,69 |
30 | 1,45 | 20 | 1,07 | 20 | 1,14 |
50 | 3,17 | 30 | 1,50 | 25 | 1,70 |
60 | 4,02 | 45 | 2,73 | 30 | 2,06 |
Table 1 continuation
1 | 2 | 3 | 4 | 5 | 6 |
80 | 5,44 | 60 | 4,07 | 45 | 3,74 |
100 | 6,68 | 90 | 5,61 | 60 | 4,93 |
120 | 7,68 | 120 | 7,02 | 80 | 6,93 |
150 | 9,15 | 158 | 8,44 | 100 | 7,83 |
180 | 9,58 | 180 | 8,77 | 120 | 8,60 |
220 | 9,89 | 220 | 9,65 | 150 | 9,53 |
[Pd (PPh3) 2Cl2] | Т=378К Т=383К =1,25∙10-2М [Pd (PPh3) 2Cl2] =1,5∙10-2М [Pd (PPh3) 2Cl2] =0 | ||||
5 | 0,11 | 5 | 0,07 | 20 | 0,05 |
10 | 0,23 | 10 | 0,11 | 40 | 0,03 |
15 | 0,44 | 15 | 0,21 | 60 | 0,03 |
20 | 0,75 | 20 | 0,49 | 90 | 0,18 |
25 | 1,03 | 25 | 0,73 | 120 | 0,25 |
30 | 1,36 | 30 | 1,11 | 150 | 0,34 |
45 | 2,69 | 45 | 2,34 | 180 | 0,35 |
60 | 3,99 | 60 | 3,59 | 210 | 0,36 |
80 | 4,96 | 85 | 5,28 | 240 | 0,42 |
100 | 5,72 | 100 | 6,80 | 270 | 0,53 |
120 | 6,85 | 120 | 7,53 | 300 | 0,55 |
150 | 8,25 | 150 | 9,63 | ||
180 | 8,96 | 180 | 9,88 | ||
220 | 9,86 | 220 | 10,00 |
Т=383К
[Pd (PPh3) 2Cl2] =1,0∙10-3М | [Pd (PPh3) 2Cl2] | =2,0∙10-3М | [Pd (PPh3) 2Cl2] = 3,0∙10-3М | ||
15 | 0,03 | 15 | 0,06 | 10 | 0,18 |
30 | 0,33 | 20 | 0,15 | 15 | 0,39 |
45 | 0,79 | 30 | 0,43 | 21 | 0,97 |
60 | 1,23 | 45 | 1,03 | 30 | 1,81 |
90 | 2,43 | 60 | 1,83 | 45 | 3,26 |
120 | 3,97 | 90 | 3,45 | 65 | 5,25 |
150 | 4,91 | 120 | 4,97 | 90 | 6,80 |
185 | 6,00 | 150 | 6,20 | 120 | 8,00 |
210 | 6,53 | 180 | 6,66 | 160 | 8,84 |
240 | 6,93 | 210 | 7,26 | 210 | 9,37 |
300 | 7,46 | 240 | 8,00 | 270 | 10,32 |
300 | 8,44 |
Table 1 continuation
1 | 2 | 3 | 4 | 5 | 6 |
Т=383К
[Pd (PPh3) 2Cl2] =4,0 ∙ 10-3 M [Pd (PPh3) 2Cl2] =6,0 ∙ 10-3 M [Pd (PPh3) 2Cl2] =8,0 ∙ 10-3 M
15 | 0,07 | 10 | 0,09 | 5 | 0,09 |
20 | 0,17 | 15 | 0,28 | 10 | 0,17 |
30 | 0,62 | 20 | 0,56 | 15 | 0,82 |
45 | 1,46 | 30 | 1,29 | 20 | 1,23 |
60 | 2,44 | 45 | 3,01 | 30 | 2,15 |
80 | 3,31 | 60 | 4,57 | 45 | 3,54 |
100 | 4,28 | 90 | 6,73 | 60 | 4,25 |
130 | 5,26 | 120 | 7,97 | 90 | 6,01 |
150 | 6,03 | 150 | 8,31 | 120 | 6,62 |
180 | 6,97 | 180 | 9,40 | 150 | 7,23 |
210 | 7,39 | 210 | 9,46 | 180 | 6,10 |
240 | 7,87 | 240 | 9,80 | 210 | 8,00 |
300 | 8,56 | 240 | 8,85 | ||
300 | 8,67 |
Т=383К Т=388К
[Pd (PPh3) 2Cl2] =1,0∙10^2М [Pd (PPh3) 2Cl2] = 1,5∙10-2М [Pd (PPh3) 2Cl2] =0
5 | 0,10 | 10 | 0, 10 | 30 | 0,07 |
10 | 0,29 | 20 | 0, 41 | 55 | 0,22 |
19 | 1,28 | 30 | 0, 84 | 70 | 0,34 |
25 | 1,93 | 40 | 1,32 | 100 | 0,53 |
30 | 2,61 | 50 | 1,87 | 140 | 0,74 |
40 | 3,55 | 65 | 2,40 | 180 | 0,85 |
50 | 4,63 | 80 | 3,07 | 220 | 0,97 |
60 | 5,35 | 100 | 3,81 | 270 | 1,10 |
75 | 6,42 | 120 | 4,39 | 320 | 1,07 |
90 | 7,24 | 155 | 5,18 | 360 | 1,19 |
110 | 8,15 | 180 | 5,72 | 400 | 1,22 |
130 | 8,63 | 210 | 6,29 | ||
150 | 9,00 | 240 | 6,66 | ||
180 | 9,33 | 300 | 7,19 | ||
240 | 9,73 | 360 | 7,61 | ||
Т=3 | 88К | ||||
[Pd (PPh3) 2Cl2] =1,0∙W3М | [Pd (PPh3) 2Cl2] | =3,0∙10^3М | [Pd (PPh3) 2Cl2 | ]= 6,0∙10^3М | |
10 | 0 10 | 5 | 0,06 | 10 | 0,24 |
20 | 0,41 | 10 | 0,12 | 15 | 0,61 |
30 | 0,84 | 15 | 0,29 | 25 | 2,15 |
Table 1 continuation
1 | 2 | 3 | 4 | 5 | 6 |
1 2 3 4 5 6
40 | 1,32 | 25 | 0,76 | 35 | 3,33 |
50 | 1,87 | 40 | 1,76 | 52 | 5,02 |
65 | 2,40 | 60 | 2,79 | 71 | 6,55 |
80 | 3,07 | 90 | 4,23 | 100 | 7,90 |
100 | 3,81 | 130 | 5,84 | 150 | 9,24 |
120 | 4,39 | 170 | 7,10 | 196 | 9,66 |
155 | 5,18 | 220 | 8,11 | 250 | 10,00 |
180 | 5,72 | 270 | 8,42 | ||
210 | 6,29 | ||||
240 | 6,66 | ||||
300 | 7,20 | ||||
360 | 7,61 |
Т=388К
[Pd (PPh3) 2Cl2] =8,0∙10-3М [Pd (PPh3) 2Cl2] =1,0∙10-2М [Pd (PPh3) 2Cl2] = 1,25∙10-2М
10 | 0 14 | 10 | 0,19 | 5 | 0,02 |
20 | 0,54 | 17 | 0,61 | 10 | 0,23 |
30 | 1,20 | 20 | 0,85 | 15 | 0,64 |
40 | 1,86 | 25 | 1,24 | 21 | 1,09 |
50 | 2,60 | 30 | 1,86 | 25 | 1,70 |
60 | 3,26 | 45 | 3,35 | 35 | 2,73 |
75 | 4,22 | 65 | 5,11 | 50 | 4,09 |
95 | 5,09 | 95 | 6,92 | 72 | 5,87 |
120 | 6,27 | 132 | 8,22 | 105 | 7,18 |
155 | 7,19 | 180 | 9,06 | 150 | 8,67 |
215 | 8,47 | 180 | 9,20 |
Т=388К Т=393К
[Pd (PPh3) 2Cl2] =1,5∙10-2М [Pd (PPh3) 2Cl2] =0 [Pd (PPh3) 2Cl2] =1,0∙10-3М
10 | 0,18 | 30 | 0,07 | 10 | 0,13 |
15 | 0,45 | 60 | 0,32 | 16 | 0,40 |
20 | 1,13 | 90 | 0,63 | 20 | 0,70 |
30 | 2,20 | 120 | 0,88 | 30 | 1,35 |
40 | 3,27 | 185 | 0,89 | 50 | 2,42 |
55 | 4,61 | 240 | 1,02 | 65 | 3,48 |
75 | 5,88 | 300 | 0,84 | 95 | 4,57 |
100 | 7,11 | 360 | 1,21 | 140 | 6,04 |
130 | 8,29 | 205 | 6,80 | ||
170 | 8,93 | 260 | 7,53 |
Table 1 continuation
1 | 2 | 3 | 4 | 5 | 6 |
245 | 9,64 | 330 | 7,54 | ||
[Pd (PPh3) 2C | Т=393К 2] =3,0∙10^3 M [Pd (PPh3) 2Cl2] = 6,0∙10^3 M [Pd (PPh3) 2Cl2] =8,0∙10 ' 3 M | ||||
5 | 0,07 | 5 | 0,09 | 5 | 0,07 |
10 | 0,35 | 10 | 0,47 | 10 | 0,41 |
15 | 1,00 | 15 | 1,27 | 15 | 0,92 |
25 | 2,20 | 20 | 1,64 | 20 | 1,62 |
35 | 3,46 | 30 | 2,82 | 30 | 3,10 |
60 | 6,09 | 45 | 4,48 | 45 | 4,77 |
75 | 7,33 | 60 | 5,45 | 65 | 6,25 |
90 | 7,76 | 90 | 6,50 | 90 | 7,44 |
120 | 8,82 | 125 | 8,32 | ||
150 | 9,37 | 170 | 9,05 | ||
180 | 9,70 |
Т=393К
[Pd (PPh3) 2Cl2] =1,0∙W2 M [Pd (PPh3) 2Cl2] = 1,25∙10-2 M [Pd (PPh3) 2Cl2] =1,5∙W2 M
5 | 0,11 | 5 | 0,19 | 5 | 0,49 |
10 | 0,51 | 10 | 0,44 | 10 | 1,22 |
15 | 1,17 | 15 | 1,14 | 15 | 2,18 |
20 | 2,07 | 20 | 1,87 | 20 | 3,16 |
26 | 2,99 | 25 | 2,86 | 30 | 4,97 |
30 | 3,58 | 30 | 3,74 | 45 | 6,67 |
40 | 4,81 | 40 | 4,70 | 60 | 7,56 |
50 | 6,08 | 55 | 5,85 | 85 | 9,38 |
60 | 6,69 | 80 | 7,12 | 120 | 9,08 |
80 | 7,92 | 110 | 8,23 | 165 | 9,38 |
100 | 8,58 | 150 | 8,83 | 220 | 9,62 |
120 | 9,56 | ||||
150 | 9,84 |
Т=398К
[Pd (PPh3) 2Cl2] =0 [Pd (PPh3) 2Cl2] =1,0∙10^3 M.
[Pd (PPh3) 2Cl2] =3,0∙10^3 M20 | 0,05 | 11 | 0,08 | 5 | 0,31 |
30 | 0,13 | 15 | 0,22 | 10 | 0,97 |
45 | 0,26 | 20 | 0,50 | 15 | 1,90 |
60 | 0,37 | 25 | 0,89 | 20 | 2,69 |
90 | 0,54 | 31 | 1,34 | 25 | 3,53 |
130 | 0,73 | 45 | 2,37 | 30 | 4,40 |
Table 1 termination
1 | 2 | 3 | 4 | 5 | 6 |
210 | 0,90 | 60 | 3,26 | 40 | 5,80 |
270 | 1,03 | 90 | 4,74 | 55 | 6,88 |
130 | 5,71 | 80 | 8,64 | ||
180 | 6,53 | 110 | 9,10 | ||
240 | 7,00 | 150 | 9,56 | ||
300 | 7,56 | 180 | 9,81 |
Т=398К
[Pd (PPh3) 2Cl2] = 6,0 ∙ 10-3 M [Pd (PPh3) 2Cl2] =8,0 ∙ 10-3 M [Pd (PPh3) 2Cl2] =1,0∙10-2М
5 | 0,47 | 5 | 0,44 | 11 | 0,08 |
15 | 2,46 | 15 | 2,32 | 15 | 0,22 |
20 | 3,48 | 20 | 3,51 | 20 | 0,50 |
25 | 4,25 | 25 | 4,53 | 25 | 0,89 |
30 | 5,07 | 30 | 5,21 | 31 | 1,34 |
40 | 6,29 | 40 | 6,41 | 45 | 2,37 |
55 | 7,47 | 55 | 7,82 | 60 | 3,26 |
85 | 8,51 | 80 | 8,59 | 90 | 4,74 |
110 | 9,28 | 110 | 9,26 | 130 | 5,71 |
150 | 9,50 | 150 | 9,41 | 180 | 6,53 |
180 | 9,77 | 180 | 9,72 | 240 | 7,00 |
300 | 7,56 |
Т=398К
[Pd (PPh3) 2Cl2] = 1,25∙10-2М [Pd (PPh3) 2Cl2] =1,5∙10-2М
5 | 0,16 | 5 | 0,32 |
10 | 0,85 | 10 | 0,97 |
15 | 1,80 | 15 | 1,93 |
20 | 2,86 | 20 | 2,76 |
25 | 3,73 | 25 | 3,62 |
30 | 4,49 | 30 | 4,57 |
40 | 5,55 | 40 | 5,41 |
55 | 6,74 | 55 | 6,65 |
80 | 8,00 | 75 | 7,70 |
110 | 8,66 | 110 | 8,60 |
150 | 9,27 | 150 | 9,15 |
Table 2. To concentration influence trifenilfosfina and temperatures for the speed gidrokarbometoksilirovanija tetrahydrobenzene.
РСо=2,00 MPa; concentration, a mole/l:
[C6Hιo] =O, 1O, [CH3OH] =O, 45, [Pd (PPh3) 2Cl2] =2, O∙lO^3, [TsOH] =2,4∙10^2
T, minute | [Ef.] Л02, Mole/l | T, minute | [Эф.р102, Mole/l | T, minute | [Ef.} 102, Mole/l |
1 | 2 | 3 | 4 | 5 | 6 |
Т=373К
[PPh3] =0 [PPh3] =5,0∙10-3 M [PPh3] = 8,0∙10-3 M
25 | 0,05 | 15 | 0,15 | 20 | 0,20 |
30 | 0,08 | 20 | 0,28 | 25 | 0,32 |
35 | 0,14 | 25 | 0,64 | 30 | 0,63 |
40 | 0,24 | 30 | 1,01 | 35 | 0,94 |
50 | 0,53 | 35 | 1,48 | 40 | 1,31 |
65 | 1,04 | 40 | 2,08 | 45 | 1,67 |
90 | 1,67 | 45 | 2,35 | 50 | 2,05 |
120 | 2,32 | 53 | 2,74 | 55 | 2,47 |
150 | 2,66 | 60 | 3,46 | 60 | 2,84 |
210 | 3,16 | 75 | 4,45 | 65 | 3,29 |
100 | 5,94 | 70 | 3,59 | ||
142 | 7,26 | 75 | 4,24 | ||
80 | 4,45 | ||||
93 | 5,56 | ||||
105 | 6,35 | ||||
130 | 7,71 | ||||
160 | 8,37 | ||||
205 | 9,33 | ||||
250 | 9,68 | ||||
310 | 9,99 |
Т=373 TO
[PPh3] = 2,0∙10-2 M [PPh3] = 5,0∙10-2 M [PPh3] = 8,0∙10-2 M
15 | 0,23 | 20 | 0,51 | 20 | 0,41 |
25 | 0,84 | 25 | 0,79 | 25 | 0,60 |
30 | 1,28 | 30 | 1,27 | 30 | 0,87 |
36 | 1,85 | 35 | 1,59 | 35 | 1,14 |
42 | 2,13 | 40 | 1,80 | 40 | 1,45 |
Table 2 continuation
1 | 2 | 3 | 4 | 5 | 6 |
46 | 2,53 | 45 | 2,17 | 45 | 1,69 |
50 | 2,97 | 55 | 3,02 | 55 | 2,32 |
60 | 3,89 | 70 | 3,95 | 70 | 3,18 |
80 | 5,46 | 90 | 5,23 | 90 | 4,23 |
100 | 6,87 | 120 | 6,35 | 120 | 5,28 |
120 | 7,86 | 160 | 7,43 | 160 | 6,65 |
170 | 9,41 | 210 | 8,21 | 210 | 7,55 |
Т=373 TO Т=378К
[PPh3] = 0,125 M [PPh3] =0 [PPh3] =0,20∙10^2М
15 | 0,10 | 20 | 0,09 | 20 | 0,06 |
25 | 0,30 | 30 | 0,34 | 30 | 0,37 |
35 | 0,62 | 50 | 0,87 | 50 | 1,27 |
47 | 1,03 | 70 | 1,39 | 70 | 2,19 |
60 | 1,61 | 90 | 1,79 | 100 | 3,04 |
75 | 2,25 | 120 | 2,12 | 130 | 3,64 |
90 | 2,96 | 180 | 2,28 | 170 | 4,15 |
105 | 3,31 | 240 | 2,57 | 200 | 4,30 |
120 | 3,81 | 280 | 4,36 | ||
150 | 4,73 | ||||
180 | 5,10 | ||||
210 | 6,20 | ||||
240 | 6,26 |
Т=378 TO
[PPh3] =0,50∙10-2М [PPh3] =0,80 ∙10^2М [PPh3] =2,0∙10^2М
20 | 0,08 | 20 | 0,18 | 20 | 0,15 |
30 | 0,50 | 30 | 0,64 | 30 | 0,40 |
50 | 1,63 | 50 | 2,06 | 45 | 1,68 |
70 | 2,62 | 70 | 3,33 | 65 | 2,86 |
100 | 3,92 | 90 | 4,68 | 90 | 4,53 |
120 | 4,53 | 120 | 6,04 | 120 | 6,29 |
150 | 5,51 | 150 | 6,84 | 160 | 7,72 |
180 | 6,04 | 190 | 8,15 | 230 | 8,76 |
210 | 6,41 | 250 | 8,45 | 270 | 9,13 |
240 | 6,72 | 330 | 8,74 | ||
300 | 7,18 |
Table 2 continuation
1 | 2 | 3 | 4 | 5 | 6 |
Т=378 TO [PPh3] = 5,0∙10-2М [PPh3] = 8,0∙10-2М [PPh3] = 0,125 M | |||||
10 | 0,15 | 20 | 0,12 | 10 | 0,03 |
22 | 0,72 | 30 | 0,34 | 20 | 0,16 |
35 | 1,55 | 46 | 0,85 | 30 | 0,34 |
45 | 2,30 | 71 | 1,72 | 45 | 0,78 |
90 | 5,61 | 100 | 2,67 | 60 | 1,28 |
110 | 6,28 | 140 | 3,60 | 80 | 1,93 |
140 | 7,65 | 190 | 5,14 | 100 | 2,49 |
180 | 8,22 | 240 | 5,87 | 120 | 3,23 |
240 | 8,74 | 150 | 3,99 | ||
270 | 9,28 | 180 | 4,48 | ||
240 | 5,67 | ||||
[PPh3] | Т=383 TO =0 [PPh3] = 2,0∙10-3М [PPh3] = 5,0∙10-3М | ||||
15 | 0,23 | 20 | 0,17 | 10 | 0,47 |
20 | 0,34 | 30 | 0,57 | 20 | 1,66 |
25 | 0,59 | 40 | 0,95 | 30 | 3,07 |
30 | 0,89 | 50 | 1,24 | 40 | 4,04 |
40 | 0,98 | 60 | 1,48 | 50 | 5,08 |
50 | 1,34 | 75 | 1,81 | 60 | 5,46 |
60 | 1,36 | 90 | 2,09 | 75 | 5,94 |
75 | 1,59 | 110 | 2,30 | 90 | 6,28 |
95 | 1,66 | 130 | 2,39 | 110 | 6,33 |
120 | 1,76 | 160 | 2,75 | ||
210 | 2,84 |
Т=383 TO
[PPh3] = 8,0∙10-3М [PPh3] = 2,0∙10-2М [PPh3] = 5,0∙10-2М
10 | 0,09 | 10 | 0,39 | 10 | 0,36 |
15 | 0,30 | 15 | 0,62 | 20 | 1,07 |
20 | 0,65 | 20 | 0,93 | 30 | 2,10 |
30 | 1,60 | 30 | 2,16 | 40 | 3,12 |
40 | 2,55 | 40 | 3,30 | 50 | 3,49 |
55 | 3,86 | 55 | 4,81 | 60 | 4,39 |
65 | 4,63 | 75 | 6,14 | 75 | 5,71 |
90 | 5,93 | 100 | 8,07 | 95 | 6,56 |
120 | 6,94 | 130 | 8,37 | 110 | 7,25 |
160 | 7,49 | 170 | 8,92 | 130 | 7,93 |
Table 2 continuation
1 | 2 | 3 | 4 | 5 | 6 |
210 | 8,30 | ||||
280 | 7,99 |
Т=388 TO
[PPh3] =0
Т=383 TO
[PPh3] = 8 M [PPh3] = 0,125 M
10 | 0,05 | 10 | 0,14 | 10 | 0,08 |
20 | 0,29 | 20 | 0,45 | 15 | 0,21 |
30 | 0,87 | 30 | 1,02 | 20 | 0,38 |
40 | 1,41 | 45 | 1,71 | 25 | 0,60 |
55 | 2,31 | 60 | 2,66 | 30 | 0,73 |
70 | 3,22 | 75 | 3,31 | 35 | 0,99 |
90 | 4,39 | 90 | 3,89 | 40 | 1,18 |
115 | 5,08 | 110 | 4,61 | 50 | 1,73 |
135 | 5,90 | 130 | 4,75 | 65 | 2,19 |
165 | 6,36 | 150 | 5,34 | 90 | 2,44 |
210 | 7,31 | ||||
265 | 7,74 |
[PPhs] = 2 3М
[PPh3] = 8,0-10-3М
Т=388 TO
[PPh3] = 5,0-10-3М
10 | 0,47 | 5 | 0,31 | 5 | 0,16 |
15 | 0,90 | 10 | 0,93 | 10 | 0,87 |
20 | 1,35 | 15 | 2,04 | 15 | 1,61 |
25 | 1,56 | 20 | 2,71 | 20 | 2,41 |
30 | 1,80 | 25 | 3,30 | 25 | 3,49 |
35 | 2,12 | 30 | 3,69 | 30 | 4,45 |
40 | 2,52 | 35 | 4,18 | 35 | 4,82 |
45 | 2,82 | 40 | 4,54 | 40 | 5,32 |
55 | 3,34 | 50 | 5,02 | 50 | 6,65 |
70 | 3,85 | 65 | 5,57 | 65 | 7,36 |
90 | 4,05 | 90 | 8,21 | ||
120 | 4,16 | 120 | 8,58 | ||
160 | 4,21 |
[PPh3] = 2 2М
[PPh3] = 8,0-10-2М
Т=388 TO
[PPh3] = 5,0-10-2М
5 | 0,23 | 10 | 0,26 | 5 | 0,07 |
10 | 0,68 | 20 | 1,28 | 10 | 0,31 |
15 | 1,22 | 30 | 2,56 | 16 | 0,74 |
20 | 1,86 | 42 | 3,82 | 20 | 1,13 |
Table 2 termination
1 | 2 | 3 | 4 | 5 | 6 |
25 | 2,51 | 53 | 4,87 | 25 | 1,76 |
30 | 3,38 | 60 | 5,37 | 31 | 2,15 |
35 | 3,96 | 75 | 6,67 | 40 | 2,84 |
40 | 4,34 | 90 | 7,51 | 55 | 4,30 |
50 | 5,79 | 120 | 8,00 | 70 | 5,35 |
65 | 7,06 | 150 | 9,00 | 90 | 6,08 |
95 | 8,34 | 180 | 8,78 | 120 | 7,41 |
115 | 8,90 | 160 | 8,25 |
Т=388 TO [PPh3] = 0,125 M
5 | 0,05 |
10 | 0,23 |
15 | 0,59 |
20 | 0,84 |
25 | 1,25 |
30 | 1,72 |
35 | 2,08 |
40 | 2,48 |
51 | 3,41 |
65 | 4,20 |
90 | 5,53 |
120 | 6,25 |
160 | 7,18 |
Table 3. To concentration influence p-toluolsulfokisloty and temperatures for the speed gidrokarbometoksilirovanija tetrahydrobenzene.
РСо=2,00 MPa; concentration, a mole/l:
[С6Ніо] =О, 1О, [SNzON] =0,45, [Pd (PPh3) 2Cl2] =l, O∙lO-3, [PPh3] =6, O∙lO-3
T, minute | [3 φ.] ∙ 102, Mole/l | T, minute | [3 φ.] ∙ 102, Mole/l | T, minute | [3 φ.] ∙ 102, Mole/l |
1 | 2 | 3 | 4 | 5 | 6 |
T=368È
[TsQH] =0,6∙10-2М [TsQH] =2,4∙10-2М [TsQH] =4,8∙10-2mol
25 | 0,03 | 20 | 0,11 | 20 | 0,24 |
35 | 0,04 | 25 | 0,17 | 25 | 0,47 |
40 | 0,06 | 30 | 0,29 | 30 | 1,22 |
45 | 0,06 | 35 | 0,60 | 35 | 1,69 |
55 | 0,10 | 40 | 0,64 | 40 | 2,22 |
70 | 0,15 | 50 | 1,38 | 50 | 3,33 |
90 | 0,25 | 70 | 2,04 | 70 | 5,15 |
120 | 0,37 | 100 | 3,51 | 100 | 7,20 |
160 | 0,57 | 140 | 4,89 | 140 | 8,55 |
210 | 0,75 | 190 | 6,05 | ||
270 | 0,89 | 250 | 7,44 | ||
330 | 1,09 | ||||
390 | 1,24 |
Т=368 TO
[TsQH] =7,2∙10-2М [TsQH] =9,6∙10-2М [TsQH] =0,12 M
10 | 0,14 | 8 | 0,03 | 8 | 0,03 |
15 | 0,56 | 10 | 0,03 | 10 | 0,05 |
20 | 1,25 | 12 | 0,09 | 12 | 0,13 |
25 | 2,11 | 15 | 0,23 | 15 | 0,31 |
30 | 2,87 | 20 | 0,99 | 20 | 1,11 |
35 | 3,69 | 25 | 1,94 | 25 | 2,10 |
40 | 4,43 | 30 | 3,09 | 30 | 3,40 |
50 | 5,92 | 40 | 5,28 | 40 | 5,70 |
65 | 8,02 | 55 | 8,94 | ||
85 | 9,05 | 80 | 9,77 | ||
110 | 9,75 | 110 | 9,69 | ||
145 | 9,96 |
1 | 2 | 3 | 4 | 5 | 6 |
Т=368 TO Т=373 TO
[Т8ОИ] =0,144 M [Т80И] =0,6Л0~2 M [Т80И] =0,12 M
10 | 0,25 | 35 | 0,04 | 25 | 0,03 |
15 | 1,50 | 40 | 0,07 | 30 | 0,08 |
20 | 2,82 | 50 | 0,10 | 35 | 0,16 |
25 | 4,33 | 70 | 0,26 | 40 | 0,21 |
30 | 5,74 | 100 | 0,35 | 45 | 0,30 |
40 | 7,92 | 140 | 0,55 | 50 | 0,37 |
50 | 8,78 | 190 | 0,85 | 60 | 0,53 |
60 | 9,07 | 250 | 1,01 | 70 | 0,72 |
80 | 9,50 | 85 | 1,01 | ||
110 | 9,56 | 100 | 1,28 | ||
150 | 9,59 | 120 | 1,67 | ||
150 | 1,98 | ||||
200 | 2,48 | ||||
230 | 2,78 | ||||
270 | 3,18 | ||||
335 | 3,23 |
Т=373 TO
∣ ' ΓsOI I ∣ 2,4 ∙ 10-2 M ∣ ' Γ sOI I ∣ 4,8 ∙ 10-2 M [Т80И] =7,2Л0~2 M
15 | 0,18 | 10 | 0,19 | 5 | 0,07 |
20 | 0,33 | 15 | 0,78 | 10 | 0,74 |
25 | 0,51 | 20 | 1,38 | 15 | 2,50 |
30 | 0,92 | 26 | 2,36 | 20 | 4,38 |
35 | 1,17 | 32 | 3,18 | 25 | 6,23 |
40 | 1,53 | 35 | 3,98 | 30 | 6,87 |
50 | 2,15 | 40 | 4,99 | 35 | 7,56 |
70 | 3,52 | 52 | 6,12 | 35 | 7,64 |
100 | 4,51 | 70 | 8,10 | 40 | 8,06 |
140 | 5,83 | 100 | 8,97 | 45 | 8,55 |
190 | 6,50 | 140 | 9,54 | 55 | 9,57 |
70 | 9,72 | ||||
100 | 9,85 |
Т=373 TO
[Т8ОИ] =9,6Л0~2 M [Т80И] =0,12 M [Т80И] =0,144 M
10 | 0,04 | 5 | 0,16 | 6 | 0,05 |
12 | 0,13 | 10 | 1,22 | 8 | 0,17 |
1 | 2 | 3 | 4 | 5 | 6 |
15 | 0,41 | 15 | 2,67 | 10 | 0,36 |
20 | 1,51 | 20 | 4,31 | 12 | 0,79 |
30 | 4,92 | 25 | 5,89 | 15 | 1,93 |
40 | 6,80 | 31 | 7,24 | 20 | 3,87 |
40 | 8,18 | 30 | 7,09 | ||
55 | 8,93 | 45 | 8,75 | ||
75 | 9,92 | 65 | 9,33 |
Т=378 TO
^sOH] =0,6∙10-2М [ΓsOH] =1,2∙10^2М [ΓsOH] =2,4∙10^2М
30 | 0,06 | 40 | 0,06 | 15 | 0,15 |
65 | 0,28 | 45 | 0,08 | 20 | 0,43 |
90 | 0,40 | 50 | 0,11 | 25 | 0,77 |
120 | 0,53 | 60 | 0,17 | 30 | 1,46 |
160 | 0,56 | 70 | 0,26 | 40 | 2,32 |
210 | 0,67 | 85 | 0,39 | 55 | 3,25 |
240 | 0,68 | 100 | 0,64 | 75 | 4,50 |
360 | 0,82 | 120 | 0,77 | 100 | 5,35 |
150 | 1,02 | 140 | 6,16 | ||
190 | 1,19 | 190 | 6,69 | ||
230 | 1,34 | 250 | 7,24 | ||
290 | 1,67 | ||||
330 | 1,87 |
Т=378 TO
^sOH] =4,8∙10-2М^sOH] =7,2∙10-2М ^sOH] =9,6∙10-2М
10 | 0,57 | 5 | 0,08 | 5 | 0,12 |
12 | 0,98 | 10 | 0,84 | 10 | 0,72 |
15 | 1,25 | 15 | 2,85 | 15 | 2,71 |
18 | 1,97 | 20 | 4,99 | 20 | 4,62 |
20 | 2,28 | 25 | 7,09 | 25 | 6,45 |
25 | 3,69 | 30 | 7,82 | 30 | 7,49 |
30 | 4,24 | 35 | 8,60 | 35 | 9,26 |
35 | 4,76 | 35 | 8,70 | 45 | 9,36 |
40 | 5,70 | 40 | 9,18 | 60 | 9,48 |
45 | 7,32 | 45 | 9,73 | 80 | 9,51 |
60 | 9,52 | 55 | 9,75 | 110 | 9,79 |
80 | 9,28 | 70 | 9,81 | 150 | 9,98 |
100 | 9,45 | 100 | 9,89 | ||
130 | 9,84 |
1 | 2 | 3 | 4 | 5 | 6 |
T=378 TO T=383 TO
[TsQH] =0,12 M [TsQH] =0,144 M [TsQH] =0,6∙10-2М
5 | 0,12 | 5 | 0,08 | 25 | 0,04 |
10 | 1,26 | 10 | 1,19 | 30 | 0,06 |
12 | 2,03 | 12 | 2,07 | 35 | 0,13 |
15 | 3,70 | 15 | 3,31 | 45 | 0,17 |
18 | 5,81 | 18 | 4,58 | 60 | 0,27 |
20 | 6,09 | 20 | 5,41 | 80 | 0,36 |
25 | 7,84 | 25 | 6,99 | 110 | 0,54 |
30 | 9,11 | 30 | 8,16 | 130 | 0,69 |
35 | 10,15 | 35 | 8,61 | 180 | 0,72 |
40 | 9,46 | ||||
45 | 9,86 | ||||
55 | 9,88 | ||||
75 | 9,89 | ||||
100 | 9,91 | ||||
130 | 9,94 |
T=383 TO
[TsQH] =1,2∙10-2М [TsQH] =2,4∙10-2М [TsQH] =4,8∙10-2М
25 | 0,04 | 10 | 0,30 | 5 | 0,23 |
30 | 0,06 | 15 | 0,32 | 10 | 0,97 |
35 | 0,13 | 20 | 0,64 | 15 | 2,30 |
40 | 0,24 | 25 | 1,03 | 20 | 3,78 |
45 | 0,38 | 30 | 1,34 | 25 | 5,17 |
50 | 0,49 | 41 | 2,37 | 30 | 6,04 |
60 | 0,71 | 55 | 3,47 | 35 | 7,57 |
70 | 1,06 | 81 | 4,87 | 45 | 8,29 |
85 | 1,31 | 100 | 6,57 | 60 | 8,18 |
100 | 1,61 | 130 | 6,32 | 80 | 8,96 |
120 | 1,81 | 170 | 6,79 | 110 | 9,10 |
150 | 2,07 | 220 | 6,82 | ||
190 | 2,26 | ||||
240 | 2,20 |
T=383 TO
[TsQH] =7,2∙10-2М [TsQH] =9,6∙10-2М [TsQH] =0,12 M
5 | 0,51 | 5 | 0,32 | 5 | 0,05 |
10 | 0,90 | 10 | 2,20 | 8 | 0,12 |
1 | 2 | 3 | 4 | 5 | 6 |
15 | 3,19 | 15 | 4,40 | 11 | 0,56 |
18 | 4,65 | 20 | 5,94 | 15 | 3,04 |
20 | 5,15 | 25 | 7,20 | 20 | 5,41 |
23 | 6,52 | 30 | 8,60 | 25 | 6,95 |
25 | 6,99 | 35 | 8,46 | 30 | 8,47 |
30 | 8,29 | 45 | 8,89 | 35 | 9,64 |
35 | 9,28 | 60 | 9,34 | 40 | 9,17 |
45 | 9,76 | 80 | 9,31 | 50 | 8,85 |
55 | 10,00 | 65 | 9,84 | ||
70 | 10,00 |
Т=383 TO Т=388 TO
^sOH] =0,14 М∏1sOH] =0,6∙10-2М ^sOH] =1,2∙10-2М
5 | 2,51 | 15 | 0,03 | 15 | 0,04 |
8 | 3,21 | 20 | 0,06 | 20 | 0,11 |
11 | 4,69 | 25 | 0,11 | 25 | 0,25 |
15 | 6,81 | 30 | 0,17 | 30 | 0,37 |
20 | 7,65 | 35 | 0,20 | 35 | 0,59 |
25 | 7,94 | 40 | 0,25 | 40 | 0,70 |
30 | 9,09 | 45 | 0,35 | 45 | 0,82 |
50 | 0,41 | 50 | 0,99 | ||
60 | 0,51 | 60 | 1,19 | ||
70 | 0,55 | 70 | 1,36 | ||
80 | 0,65 | 80 | 1,48 | ||
90 | 0,69 | 95 | 1,61 | ||
150 | 0,77 | 110 | 1,71 | ||
190 | 0,81 | 130 | 1,84 | ||
240 | 0,86 | 160 | 1,87 | ||
317 | 0,85 | 200 | 1,83 |
Т=388 TO
^sOH] =2,4∙10-2М^sOH] =4,8∙10-2М ^sOH] =7,2∙10-2М
4 | 0,06 | 6 | 0,05 | 4 | 0,16 |
6 | 0,10 | 9 | 0,32 | 6 | 0,72 |
9 | 0,21 | 12 | 1,19 | 9 | 2,01 |
12 | 0,50 | 15 | 1,95 | 12 | 3,22 |
15 | 0,83 | 20 | 3,35 | 15 | 4,58 |
20 | 1,46 | 25 | 5,07 | 20 | 6,45 |
25 | 2,17 | 30 | 5,88 | 25 | 7,54 |
Table 3 termination
1 | 2 | 3 | 4 | 5 | 6 |
30 | 2,47 | 40 | 7,32 | 33 | 7,85 |
40 | 3,38 | 50 | 7,48 | 40 | 8,46 |
50 | 4,23 | 80 | 9,17 |
[Т8ОИ] =9,6Л0~2 M
[Т8ОИ] =0,14 M
Т=388 TO [Т80И] =0,12 M
5 | 0,61 | 2 | 0,17 | 2 | 0,07 |
10 | 2,43 | 4 | 1,08 | 4 | 0,63 |
15 | 5,38 | 6 | 2,46 | 6 | 1,67 |
20 | 6,94 | 8 | 3,82 | 8 | 3,27 |
25 | 8,12 | 10 | 5,68 | 10 | 4,50 |
30 | 8,09 | 13 | 6,68 | 13 | 6,98 |
40 | 9,00 | 16 | 7,33 | 16 | 7,38 |
50 | 8,98 | 20 | 8,14 | 20 | 7,87 |
65 | 9,56 | 25 | 8,58 | 25 | 8,31 |
85 | 9,18 | 35 | 8,72 | 35 | 8,42 |
120 | 8,85 | 50 | 9,08 | 50 | 8,39 |
Table 4. To influence of concentration of free water on speed gidrokarbometoksilirovanija tetrahydrobenzene.
Т=378 To; РСо=2,00 MPa; concentration, a mole/l: [С6Ніо] =О, 1О, [SNzON] =0,45, [Pd (PPha) IChJ=M-IO ' 3, [PPhaJ=M-IO ' 3,
[TsOH] =2,4∙10 ' 2
T, minute | [3 φ.] ∙ 102, Mole/l | T, minute | [3 φ.] ∙ 102, Mole/l | T, minute | [3 φ.] ∙ 102, Mole/l |
1 | 2 | 3 | 4 | 5 | 6 |
[H2Q] =1,2∙10^2М [H2Q] =2,4∙10^2М [H2Q] =3,0∙10^2М
20 | 0,05 | 10 | 0,02 | 15 | 0,06 |
25 | 0,09 | 15 | 0,02 | 20 | 0,25 |
30 | 0,28 | 20 | 0,04 | 25 | 0,49 |
35 | 0,46 | 25 | 0,09 | 30 | 0,68 |
40 | 0,66 | 30 | 0,25 | 35 | 1,06 |
50 | 0,86 | 40 | 0,64 | 40 | 1,42 |
60 | 1,38 | 55 | 1,47 | 50 | 2,04 |
70 | 1,77 | 70 | 2,36 | 60 | 2,85 |
85 | 2,44 | 90 | 2,83 | 70 | 3,25 |
110 | 3,59 | 105 | 3,32 | 85 | 4,02 |
140 | 3,74 | 120 | 3,36 | 110 | 4,88 |
180 | 4,22 | 135 | 3,79 | 140 | 5,36 |
230 | 4,80 | 154 | 4,03 | 180 | 5,39 |
290 | 4,89 | 200 | 4,18 | 230 | 5,66 |
350 | 4,98 | 240 | 5,09 | 290 | 5,77 |
285 | 4,79 | ||||
340 | 4,73 |
[H2Q] =4,8∙10^2М [H2Q] =5,9∙10^2М [H2Q] =7,2∙10^2М
20 | 0,03 | 15 | 0,23 | 25 | 0,23 |
25 | 0,15 | 20 | 0,47 | 30 | 0,30 |
30 | 0,36 | 25 | 0,78 | 35 | 0,51 |
40 | 0,90 | 30 | 1,11 | 40 | 0,67 |
57 | 1,77 | 35 | 1,44 | 45 | 0,94 |
70 | 2,31 | 40 | 1,73 | 50 | 1,07 |
85 | 2,60 | 45 | 2,19 | 60 | 1,39 |
100 | 2,82 | 50 | 2,40 | 70 | 1,69 |
120 | 3,03 | 60 | 2,91 | 85 | 1,93 |
Table 4 continuation
1 | 2 | 3 | 4 | 5 | 6 |
150 | 3,33 | 70 | 3,44 | 110 | 2,12 |
190 | 3,60 | 80 | 3,73 | 150 | 2,29 |
240 | 3,55 | 95 | 3,89 | 190 | 2,37 |
120 | 4,32 | 250 | 2,48 | ||
150 | 4,59 | 310 | 2,57 | ||
190 | 4,48 |
[H2Q] =8,2∙10-2М [H2Q] =9,0∙10-2М [H2Q] =9,6∙10^2М
10 | 0,02 | 15 | 0,12 | 25 | 0,18 |
15 | 0,08 | 25 | 1,10 | 30 | 0,32 |
20 | 0,19 | 30 | 1,65 | 35 | 0,48 |
25 | 0,34 | 35 | 2,44 | 40 | 0,70 |
30 | 0,64 | 40 | 2,81 | 45 | 0,79 |
35 | 0,80 | 45 | 3,33 | 50 | 1,06 |
40 | 0,97 | 50 | 3,74 | 55 | 1,21 |
45 | 1,20 | 60 | 4,52 | 60 | 1,35 |
50 | 1,43 | 70 | 5,50 | 70 | 1,50 |
60 | 1,76 | 85 | 6,33 | 85 | 1,69 |
70 | 2,06 | 110 | 7,08 | 110 | 1,95 |
85 | 2,52 | 140 | 7,26 | 140 | 2,05 |
110 | 2,80 | 180 | 7,60 | 180 | 2,19 |
140 | 3,06 | 240 | 7,86 | 230 | 2,34 |
185 | 3,60 | 290 | 7,89 | 290 | 2,35 |
230 | 3,69 | 350 | 8,67 | ||
290 | 4,18 | ||||
350 | 4,27 | ||||
410 | 4,27 |
[¾Q] =0,12 M
[H2Q] =0,122 M
25 | 0,13 | 20 | 1,01 |
30 | 0,20 | 25 | 1,47 |
35 | 0,29 | 30 | 1,79 |
40 | 0,43 | 35 | 2,24 |
45 | 0,58 | 40 | 2,70 |
50 | 0,67 | 45 | 3,09 |
55 | 0,81 | 50 | 3,46 |
60 | 0,90 | 60 | 4,06 |
72 | 1,04 | 70 | 4,79 |
Table 4 termination
1 | 2 | 3 | 4 |
85 | 1,10 | 85 | 5,63 |
110 | 1,19 | 110 | 6,48 |
160 | 1,30 | 140 | 7,09 |
180 | 1,37 | 180 | 7,38 |
230 | 1,40 | 230 | 7,59 |
290 | 8,02 | ||
350 | 7,99 |
Table 5. To influence of pressure WITH and temperatures for the speed gidrokarbometoksilirovanija tetrahydrobenzene.
Concentration, a mole/l: [С6Н10] =0,10; [СН3ОН] =0,45, [Pd (PPh3) 2Cl2] =2,0∙10^3, [PPh3] =8,0∙10 ' 3, [TsOH] =2,4∙10 ' 2
T, minute | [3 φ.] ∙ι o2, Mole/l | T, minute | [Ef.]-102, Mole/l | T, minute | [Ef.]-102, Mole/l |
1 | 2 | 3 | 4 | 5 | 6 |
Т=368К
Pco=0,50МПа Pco=1,00МПа Pco=2,00МПа
40 | 0,06 | 20 | 0,08 | 15 | 0,14 |
50 | 0,12 | 30 | 0,37 | 20 | 0,24 |
60 | 0,22 | 40 | 0,89 | 30 | 0,52 |
80 | 0,62 | 50 | 1,48 | 40 | 0,97 |
110 | 1,01 | 60 | 1,80 | 50 | 1,58 |
150 | 1,71 | 80 | 2,91 | 60 | 2,26 |
200 | 3,23 | 110 | 4,73 | 75 | 3,29 |
260 | 4,74 | 150 | 6,72 | 100 | 4,76 |
320 | 6,14 | 200 | 9,09 | 130 | 6,29 |
380 | 6,99 | 260 | 9,52 | 170 | 8,21 |
320 | 9,85 | 220 | 9,23 | ||
280 | 9,28 |
Т=368 TO
Pco—3,00 MPa Pco—4,00 Mlla Pco—5,00 Mlla
15 | 0,05 | 15 | 0,11 | 20 | 0,06 |
20 | 0,12 | 20 | 0,10 | 30 | 0,08 |
30 | 0,44 | 25 | 0,17 | 40 | 0,16 |
40 | 0,74 | 35 | 0,43 | 50 | 0,27 |
50 | 1,58 | 45 | 0,70 | 65 | 0,46 |
60 | 1,93 | 60 | 1,19 | 85 | 0,86 |
75 | 2,76 | 80 | 1,89 | 110 | 1,53 |
100 | 2,99 | 110 | 3,24 | 140 | 2,20 |
130 | 5,41 | 155 | 4,50 | 180 | 3,20 |
170 | 7,02 | 201 | 5,73 | 230 | 4,55 |
220 | 7,99 | 260 | 6,50 | 290 | 5,69 |
1 | 2 | 3 | 4 | 5 | 6 |
320 | 7,24 | 350 | 6,98 | ||
380 | 8,44 | 410 | 7,87 | ||
440 | 8,92 | 470 | 8,10 |
Т=368 TO Т=373 TO
Pco=6,00МПа Pco=0,50МПа Pco=1,00МПа
45 | 0,40 | 30 | 0,07 | 25 | 0,02 |
50 | 0,47 | 35 | 0,13 | 30 | 0,05 |
55 | 0,60 | 40 | 0,19 | 35 | 0,15 |
60 | 0,66 | 45 | 0,27 | 45 | 0,41 |
70 | 0,85 | 50 | 0,35 | 60 | 1,01 |
80 | 1,00 | 60 | 0,53 | 80 | 2,16 |
110 | 1,54 | 75 | 0,82 | 110 | 3,68 |
140 | 2,05 | 100 | 1,35 | 150 | 5,32 |
180 | 2,71 | 130 | 2,00 | 200 | 7,06 |
231 | 3,63 | 170 | 2,96 | 260 | 8,26 |
293 | 4,46 | 220 | 3,83 | 320 | 8,43 |
280 | 4,92 | ||||
340 | 6,13 | ||||
400 | 6,39 |
Т=373 TO
Pco=2,00МПа Pco=3,00МПа Pco=4,00МПа
25 | 0,75 | 10 | 0,10 | 5 | 0,04 |
35 | 1,50 | 15 | 0,29 | 10 | 0,19 |
40 | 1,96 | 20 | 0,54 | 15 | 0,38 |
45 | 2,44 | 30 | 1,21 | 20 | 0,68 |
50 | 2,84 | 40 | 1,94 | 30 | 1,42 |
55 | 3,29 | 50 | 2,78 | 40 | 2,50 |
60 | 3,78 | 60 | 3,74 | 50 | 3,51 |
70 | 4,53 | 75 | 4,29 | 60 | 4,78 |
90 | 5,75 | 100 | 5,63 | 75 | 5,79 |
120 | 7,04 | 130 | 7,42 | 100 | 6,68 |
166 | 7,77 | 170 | 8,17 | 130 | 7,89 |
220 | 8,88 | 170 | 8,54 | ||
220 | 8,64 | ||||
280 | 9,49 | ||||
340 | 9,78 |
1 | 2 | 3 | 4 | 5 | 6 |
Т=373 TO Т=378К
Pco=5,00МПа Pco=6,00МПа Pco=0,50МПа
10 | 0,08 | 10 | 0,04 | 45 | 0,04 |
15 | 0,14 | 15 | 0,11 | 60 | 0,08 |
20 | 0,37 | 20 | 0,23 | 80 | 0,21 |
30 | 0,84 | 25 | 0,35 | 110 | 0,60 |
40 | 1,17 | 35 | 0,66 | 150 | 1,29 |
50 | 1,70 | 50 | 0,95 | 200 | 2,58 |
60 | 2,10 | 60 | 0,78 | 260 | 3,49 |
75 | 3,02 | 77 | 1,73 | 320 | 4,61 |
100 | 4,10 | 101 | 2,10 | 380 | 6,11 |
130 | 5,50 | 130 | 2,75 | ||
160 | 6,28 | 175 | 3,66 | ||
220 | 7,33 | 235 | 4,48 | ||
280 | 7,60 | 280 | 5,43 | ||
340 | 5,89 |
Т=378 TO
Pco=1,00МПа Pco=2,00МПа Pco=3,00МПа
20 | 0,13 | 20 | 0,15 | 10 | 0,38 |
25 | 0,33 | 30 | 0,56 | 15 | 0,70 |
30 | 0,49 | 50 | 1,81 | 20 | 1,19 |
35 | 0,73 | 70 | 2,93 | 30 | 2,19 |
40 | 0,99 | 90 | 4,11 | 40 | 3,31 |
50 | 1,59 | 120 | 5,31 | 50 | 4,72 |
70 | 2,79 | 150 | 6,01 | 60 | 5,28 |
100 | 4,99 | 190 | 7,16 | 75 | 6,23 |
140 | 6,65 | 250 | 7,42 | 100 | 7,39 |
190 | 7,69 | 330 | 7,68 | 130 | 8,24 |
250 | 9,20 | 170 | 9,16 | ||
310 | 9,12 | 220 | 9,38 |
Т=378 TO
Pco=4,00МПа Pco=5,00МПа Pco=6,00МПа
5 | 0,04 | 5 | 0,05 | 10 | 0,20 |
10 | 0,23 | 10 | 0,15 | 15 | 0,31 |
15 | 0,53 | 15 | 0,32 | 20 | 0,45 |
20 | 0,87 | 20 | 0,60 | 25 | 0,68 |
1 | 2 | 3 | 4 | 5 | 6 |
Pco=0,50МПа
Pco=2,00МПа
60 | 0,11 | 15 | 0,14 | 10 | 0,07 |
80 | 0,46 | 20 | 0,40 | 15 | 0,25 |
110 | 0,99 | 25 | 0,90 | 20 | 0,80 |
150 | 2,23 | 35 | 1,83 | 25 | 1,10 |
200 | 3,50 | 45 | 2,42 | 31 | 1,78 |
260 | 4,63 | 60 | 3,26 | 35 | 2,50 |
80 | 3,87 | 40 | 2,68 | ||
110 | 4,68 | 50 | 3,53 | ||
150 | 4,80 | 65 | 4,56 | ||
200 | 4,62 | 90 | 6,05 | ||
260 | 5,44 | 130 | 7,65 | ||
160 | 8,28 | ||||
210 | 8,30 | ||||
270 | 8,59 |
Pco=3,00МПа
Pco=5,00МПа
Т=383 TO
Pco=4,00МПа
7 | 0,27 | 5 | 0,14 | 5 | 0,09 |
10 | 0,45 | 10 | 0,51 | 10 | 0,26 |
15 | 1,00 | 15 | 1,11 | 15 | 0,62 |
20 | 1,53 | 20 | 1,66 | 20 | 0,97 |
25 | 2,39 | 25 | 2,22 | 25 | 1,47 |
30 | 2,65 | 30 | 2,70 | 30 | 2,16 |
40 | 4,00 | 35 | 3,29 | 35 | 2,57 |
50 | 4,89 | 45 | 4,16 | 40 | 3,04 |
1 | 2 | 3 | 4 | 5 | 6 |
70 | 6,64 | 60 | 5,90 | 45 | 3,37 |
100 | 7,70 | 80 | 7,03 | 55 | 3,94 |
140 | 8,86 | 110 | 8,41 | 70 | 4,92 |
190 | 9,02 | 150 | 9,05 | 90 | 5,94 |
250 | 9,27 | 200 | 9,21 | 120 | 6,71 |
160 | 7,69 | ||||
210 | 8,55 | ||||
270 | 9,02 |
Т=383 TO Т=388 TO
Pco=6,00МПа Pco=0,50МПа Pco=1,00МПа
5 | 0,04 | 40 | 0,08 | 15 | 0,12 |
10 | 0,23 | 50 | 0,27 | 20 | 0,34 |
15 | 0,57 | 65 | 0,48 | 25 | 0,71 |
20 | 1,02 | 90 | 1,15 | 30 | 1,12 |
25 | 1,71 | 120 | 1,87 | 35 | 1,54 |
30 | 1,98 | 160 | 3,02 | 40 | 1,85 |
35 | 2,61 | 210 | 4,23 | 50 | 2,56 |
40 | 3,23 | 270 | 5,15 | 65 | 3,53 |
50 | 4,18 | 330 | 6,04 | 90 | 4,89 |
65 | 5,34 | 390 | 6,73 | 120 | 5,84 |
90 | 6,67 | 160 | 6,49 | ||
120 | 7,87 | 210 | 7,09 | ||
160 | 8,58 | 270 | 7,22 | ||
210 | 8,97 | ||||
270 | 9,17 |
Т=388 TO
Pco=2,00МПа Pco=3,00МПа Pco=4,00МПа
5 | 0,14 | 5 | 0,26 | 5 | 0,20 |
10 | 0,76 | 10 | 0,86 | 10 | 0,75 |
15 | 1,42 | 15 | 1,54 | 15 | 1,63 |
20 | 2,11 | 20 | 2,49 | 20 | 2,53 |
25 | 3,06 | 25 | 3,08 | 25 | 3,27 |
30 | 3,91 | 30 | 3,63 | 30 | 4,13 |
35 | 4,23 | 35 | 4,47 | 35 | 5,12 |
40 | 4,68 | 40 | 4,82 | 40 | 5,80 |
50 | 5,85 | 50 | 5,83 | 45 | 6,58 |
65 | 6,47 | 65 | 7,35 | 55 | 6,91 |
Table 5 termination
1 | 2 | 3 | 4 | 5 | 6 |
90 | 7,21 | 90 | 7,78 | 70 | 7,27 |
120 | 7,54 | 120 | 8,20 | 90 | 8,11 |
160 | 9,07 | 120 | 8,26 | ||
160 | 8,79 |
Т=388 TO
Pco=5,00МПа
Pco=6,00МПа
5 | 0,12 | 5 | 0,12 | ||||
10 | 0,43 | 10 | 0,45 | ||||
15 | 1,03 | 15 | 0,99 | ||||
20 | 1,92 | 20 | 1,59 | ||||
25 | 2,22 | 25 | 2,20 | ||||
30 | 2,82 | 30 | 2,82 | ||||
35 | 3,39 | 35 | 3,26 | ||||
40 | 4,17 | 45 | 4,14 | ||||
45 | 5,09 | 60 | 5,20 | ||||
55 | 6,47 | 80 | 6,08 | ||||
70 | 6,85 | 110 | 6,90 | ||||
90 | 7,25 | 150 | 7,56 | ||||
120 | 8,03 | 210 | 8,54 | ||||
160 | 8,59 | 270 | 7,83 | ||||
210 | 8,53 | ||||||
270 | 8,79 | ||||||
25 | 1,45 | 25 | 0,93 | 30 | 0,82 | ||
30 | 1,83 | 30 | 1,31 | 35 | 1,04 | ||
40 | 2,59 | 35 | 1,71 | 45 | 1,37 | ||
50 | 3,25 | 45 | 2,47 | 60 | 1,90 | ||
60 | 4,21 | 60 | 4,05 | 80 | 2,52 | ||
75 | 5,22 | 80 | 4,88 | 110 | 3,34 | ||
100 | 6,45 | 110 | 6,15 | 150 | 4,77 | ||
130 | 7,47 | 150 | 7,42 | 220 | 5,19 | ||
170 | 8,70 | 200 | 8,58 | 270 | 5,86 | ||
220 | 9,46 | 260 | 9,59 | ||||
240 | 9,53 | ||||||
Т=383 TO
Pco=1,00МПа
Table 6. To influence of concentration of methanol and temperatures for the speed gidrokarbometoksilirovanija tetrahydrobenzene.
РСо=2,00 MPa; concentration, a mole/l:
[С6Ніо] =О, 1О, [Pd (PPh3) 2Cl2] =2, O∙lO^3, [PPh3] =8, O∙lO^3, [TsOH] =2,4∙10^2
T, minute | [Ef.]-102, Mole/l | T, minute | [Ef.]-102, Mole/l | T, minute | [Ef.]-102, Mole/l |
1 | 2 | 3 | 4 | 5 | 6 |
Т=358К
[CH3OH] =3,0∙10-2М [CH3OH] = 7,5∙10-2М [CH3OH] =0,15 M
80 | 0,04 | 50 | 0,10 | 50 | 0,03 |
90 | 0,21 | 60 | 0,50 | 75 | 0,24 |
110 | 0,63 | 70 | 0,88 | 90 | 0,67 |
130 | 1,30 | 80 | 1,49 | 110 | 1,97 |
150 | 1,93 | 90 | 2,02 | 140 | 4,75 |
170 | 2,45 | 100 | 2,73 | 160 | 6,50 |
200 | 2,55 | 110 | 3,22 | 180 | 7,89 |
122 | 3,81 | 220 | 8,93 | ||
132 | 4,28 | 260 | 9,52 | ||
140 | 4,63 | ||||
160 | 5,60 | ||||
190 | 6,39 | ||||
230 | 7,04 |
Т=358 TO
[cH3oH] =0, 20 M [cH3oH] = 0,30 M [cH3oH] = 0,45 M
25 | 0,03 | 45 | 0,22 | 70 | 0,11 |
35 | 0,14 | 50 | 0,28 | 80 | 0,23 |
40 | 0,28 | 60 | 0,49 | 90 | 0,31 |
50 | 0,62 | 70 | 0,82 | 104 | 0,49 |
60 | 1,06 | 80 | 1,08 | 120 | 0,72 |
75 | 1,97 | 90 | 1,46 | 140 | 1,17 |
90 | 3,06 | 110 | 2,30 | 160 | 1,70 |
110 | 3,97 | 140 | 3,93 | 190 | 2,36 |
140 | 6,51 | 180 | 5,49 | 220 | 3,19 |
180 | 8,13 | 230 | 7,22 | 260 | 4,11 |
240 | 9,02 | 290 | 8,73 | 300 | 4,93 |
1 | 2 | 3 | 4 | 5 | 6 |
330 | 9,17 | 350 | 5,85 | ||
420 | 6,97 |
Т=358 TO Т=363 TO
[CH3OH] = 0,60 M [CH3OH] = 0,90 M [CH3OH] = 3,0 ∙10^2М
50 | 0,03 | 50 | 0,05 | 14 | 0,04 |
60 | 0,15 | 60 | 0,08 | 17 | 0,07 |
70 | 0,27 | 70 | 0,15 | 20 | 0,14 |
85 | 0,40 | 80 | 0,20 | 25 | 0,30 |
100 | 0,64 | 95 | 0,30 | 30 | 0,49 |
120 | 1,00 | 110 | 0,47 | 35 | 0,62 |
150 | 1,54 | 130 | 0,72 | 40 | 0,83 |
190 | 2,28 | 150 | 0,89 | 50 | 1,37 |
240 | 3,24 | 180 | 1,13 | 60 | 2,04 |
300 | 4,28 | 220 | 1,57 | 75 | 2,28 |
360 | 5,22 | 270 | 2,04 | 100 | 2,55 |
420 | 5,99 | 330 | 2,43 | 125 | 2,48 |
450 | 6,01 | 390 | 2,86 | 160 | 2,74 |
450 | 3,46 | 190 | 2,56 |
Т=363 TO
[CH3OH] = 7,5∙10-2М [CH3OH] = 0,10 M [CH3OH] = 0,15 M
20 | 0,26 | 10 | 0,12 | 5 | 0,01 |
25 | 0,48 | 15 | 0,24 | 10 | 0,10 |
30 | 0,78 | 20 | 0,43 | 15 | 0,22 |
35 | 1,17 | 25 | 0,65 | 20 | 0,48 |
40 | 1,60 | 30 | 0,88 | 25 | 0,70 |
45 | 2,01 | 35 | 1,24 | 30 | 1,10 |
50 | 2,42 | 40 | 1,55 | 35 | 1,44 |
55 | 2,86 | 45 | 1,80 | 40 | 1,74 |
60 | 3,25 | 50 | 2,21 | 45 | 2,25 |
65 | 3,58 | 60 | 2,87 | 50 | 2,76 |
70 | 4,04 | 75 | 4,18 | 60 | 3,98 |
75 | 4,31 | 90 | 5,16 | 75 | 5,10 |
85 | 5,01 | 110 | 6,04 | 90 | 6,41 |
100 | 6,42 | 140 | 6,84 | 110 | 7,61 |
120 | 6,27 | 180 | 7,42 | 140 | 8,67 |
150 | 6,89 | 220 | 7,39 | 180 | 9,22 |
190 | 7,28 |
1 | 2 | 3 | 4 | 5 | 6 |
[CH3OH] | Т—3 ( — 0,20 M [CH3OH] | 53 TO —0, 30 M [CH3OH] | — 0,45 M | ||
10 | 0,05 | 20 | 0,10 | 30 | 0,04 |
15 | 0,09 | 25 | 0,25 | 35 | 0,09 |
20 | 0,19 | 30 | 0,36 | 40 | 0,16 |
25 | 0,42 | 35 | 0,45 | 45 | 0,23 |
30 | 0,77 | 40 | 0,63 | 50 | 0,38 |
35 | 1,02 | 45 | 0,89 | 55 | 0,52 |
40 | 1,49 | 50 | 1,16 | 60 | 0,67 |
45 | 1,91 | 55 | 1,39 | 65 | 0,81 |
50 | 2,27 | 60 | 1,70 | 70 | 0,89 |
55 | 2,79 | 65 | 1,97 | 75 | 1,00 |
60 | 3,17 | 70 | 2,32 | 80 | 1,25 |
65 | 3,77 | 80 | 3,17 | 90 | 1,63 |
70 | 4,18 | 90 | 4,06 | 110 | 2,35 |
80 | 5,34 | 110 | 5,56 | 140 | 3,50 |
95 | 6,43 | 140 | 6,87 | 180 | 4,75 |
110 | 7,88 | 180 | 8,40 | 230 | 5,97 |
140 | 8,56 | 210 | 9,04 | 290 | 7,05 |
185 | 9,17 | 350 | 7,82 | ||
230 | 9,13 |
Т=363 TO Т=368 TO
[CH3OH] = 0,60 M [CH3OH] =0, 90 M [CH3OH] =3,0∙10-2М
50 | 0,11 | 60 | 0,03 | 5 | 0,03 |
55 | 0,15 | 75 | 0,08 | 8 | 0,08 |
60 | 0,20 | 90 | 0,14 | 11 | 0,20 |
65 | 0,30 | 110 | 0,25 | 14 | 0,47 |
70 | 0,34 | 130 | 0,40 | 17 | 0,69 |
80 | 0,53 | 165 | 0,75 | 22 | 1,10 |
90 | 0,79 | 200 | 1,04 | 27 | 1,60 |
100 | 1,08 | 250 | 1,77 | 32 | 2,01 |
110 | 1,35 | 310 | 2,53 | 37 | 2,09 |
120 | 1,70 | 370 | 2,95 | 45 | 2,17 |
130 | 2,25 | 430 | 3,46 | 55 | 2,17 |
140 | 2,62 | 490 | 3,85 | 70 | 2,37 |
150 | 3,14 | 550 | 4,48 | 90 | 2,30 |
170 | 4,37 | 120 | 2,23 | ||
210 | 6,55 |
1 | 2 | 3 | 4 | 5 | 6 |
240 | 7,32 | ||||
270 | 7,39 | ||||
300 | 7,61 | ||||
340 | 7,52 |
Т=368 TO
[CH3OH] =7,5∙10-2М | [CH30H] =0,10 M | [CH3OH] =0,15 M | |||
15 | 0,73 | 10 | 0,51 | 10 | 0,13 |
20 | 1,00 | 15 | 0,22 | 15 | 0,46 |
25 | 1,49 | 20 | 0,48 | 20 | 1,00 |
30 | 2,42 | 25 | 0,98 | 25 | 1,45 |
35 | 3,01 | 30 | 1,55 | 30 | 1,88 |
40 | 3,27 | 35 | 2,21 | 35 | 2,55 |
50 | 4,13 | 45 | 3,55 | 40 | 3,17 |
60 | 4,80 | 60 | 4,89 | 45 | 3,87 |
70 | 5,35 | 80 | 6,09 | 55 | 5,09 |
90 | 5,49 | 115 | 7,07 | 70 | 7,03 |
120 | 5,75 | 140 | 7,00 | 90 | 8,04 |
160 | 5,55 | 180 | 8,61 | 120 | 9,18 |
160 | 9,51 | ||||
210 | 9,53 | ||||
Т=368 TO | |||||
[CH3OH] | =0,20 M | [CH3OH] | =0,30 M | [CH3OH] =0,45 M | |
10 | 0,29 | 15 | 0,42 | 30 | 0,10 |
15 | 0,46 | 20 | 0,67 | 35 | 0,24 |
20 | 0,78 | 25 | 0,97 | 40 | 0,37 |
25 | 1,18 | 30 | 1,01 | 45 | 0,56 |
30 | 1,67 | 35 | 1,37 | 50 | 0,74 |
35 | 2,21 | 40 | 1,82 | 55 | 0,94 |
40 | 2,89 | 45 | 2,22 | 60 | 1,12 |
45 | 3,40 | 55 | 3,14 | 65 | 1,33 |
50 | 3,95 | 70 | 4,45 | 70 | 1,50 |
55 | 4,59 | 90 | 6,24 | 75 | 1,78 |
60 | 5,10 | 120 | 8,06 | 80 | 2,19 |
65 | 5,61 | 160 | 8,75 | 90 | 2,63 |
70 | 6,19 | 210 | 9,17 | 105 | 3,17 |
80 | 6,88 | 130 | 4,44 | ||
95 | 8,06 | 160 | 5,43 |
1 | 2 | 3 | 4 | 5 | 6 |
110 | 8,54 | 200 | 6,52 | ||
140 | 9,49 | 250 | 7,90 | ||
180 | 10,16 | 310 | 8,46 |
Т=368 TO Т=373 TO
[CH3OH] =0,60 M [CH3OH] =0,90 M [CH3OH] =3,0∙10^2М
30 | 0,05 | 20 | 0,09 | 5 | 0,17 |
35 | 0,11 | 30 | 0,21 | 10 | 0,50 |
40 | 0,15 | 40 | 0,40 | 15 | 0,85 |
45 | 0,19 | 50 | 0,47 | 20 | 1,34 |
55 | 0,52 | 65 | 0,91 | 25 | 1,73 |
70 | 0,98 | 80 | 1,04 | 30 | 2,16 |
90 | 1,75 | 110 | 1,70 | 35 | 2,32 |
120 | 3,17 | 120 | 2,21 | 40 | 2,47 |
160 | 4,50 | 150 | 2,83 | 50 | 2,71 |
210 | 6,08 | 180 | 3,54 | 60 | 2,70 |
270 | 7,89 | 210 | 4,40 | 75 | 3,17 |
330 | 8,80 | 240 | 4,55 | 120 | 2,85 |
390 | 9,11 | 300 | 5,48 | 160 | 3,33 |
360 | 5,94 | ||||
Т=373 TO [CH3OH] =7,5∙10-2М [CH3OH] =0,10 M [CH3OH] | =0,15 M | ||||
10 | 0,10 | 10 | 0,05 | 10 | 0,03 |
15 | 0,26 | 15 | 0,40 | 15 | 0,09 |
20 | 0,49 | 20 | 0,81 | 20 | 0,26 |
25 | 1,21 | 25 | 1,55 | 25 | 0,47 |
30 | 1,56 | 30 | 2,08 | 30 | 0,68 |
35 | 2,00 | 35 | 3,09 | 40 | 2,15 |
45 | 3,19 | 45 | 4,70 | 50 | 3,38 |
60 | 4,35 | 60 | 6,13 | 60 | 4,69 |
95 | 5,93 | 80 | 6,80 | 75 | 6,02 |
120 | 6,05 | 110 | 8,10 | 100 | 7,76 |
140 | 5,78 | 150 | 9,43 | 130 | 8,68 |
180 | 6,26 | 200 | 9,44 | 170 | 9,96 |
220 | 9,58 |
1 | 2 | 3 | 4 | 5 | 6 |
[CH3OH | Т—373 TO []—0,20 M [CH3OH]—0,30 M [CH3OH | :]—o, 4O m | |||
15 | 1,10 | 15 | 0,10 | 20 | 0,17 |
20 | 1,49 | 20 | 0,36 | 25 | 0,28 |
25 | 2,01 | 25 | 0,71 | 30 | 0,55 |
30 | 2,55 | 30 | 1,19 | 35 | 0,82 |
35 | 3,16 | 35 | 1,58 | 40 | 1,15 |
40 | 3,69 | 40 | 2,22 | 45 | 1,47 |
45 | 4,22 | 45 | 2,65 | 50 | 1,80 |
50 | 4,76 | 55 | 3,98 | 55 | 2,17 |
55 | 5,26 | 70 | 4,96 | 60 | 2,49 |
60 | 5,69 | 90 | 6,54 | 65 | 2,89 |
65 | 6,06 | 12O | 8,78 | 70 | 3,15 |
70 | 6,43 | 16O | 9,42 | 75 | 3,73 |
75 | 6,74 | 21O | 9,89 | 80 | 3,91 |
85 | 7,28 | 285 | 9,63 | 93 | 4,89 |
100 | 7,71 | 1O5 | 5,58 | ||
120 | 8,28 | 13O | 6,78 | ||
150 | 8,40 | 16O | 7,35 | ||
190 | 8,63 | 2O5 | 8,20 | ||
25O | 8,51 | ||||
31O | 8,83 |
Т—373 TO Т—378 TO
[CH3OH]—0,60 M [CH3OH]—O, 9O M [CH3OH] =3,0∙10-2М
20 | 0,11 | 1O | O, O9 | 5 | O, O6 |
25 | 0,23 | 20 | 0,27 | 8 | 0,27 |
30 | O, 4O | 30 | 0,55 | 11 | O, 4O |
35 | 0,55 | 40 | O, 8O | 14 | O, 7O |
40 | O, 8O | 50 | 1,08 | 17 | 0,95 |
45 | 1,05 | 65 | 1,66 | 22 | 1,46 |
55 | 1,56 | 80 | 2,19 | 27 | 1,77 |
65 | 2,26 | 1OO | 3,29 | 32 | 2,11 |
80 | 2,97 | 12O | 3,50 | 37 | 2,15 |
1OO | 4,14 | 15O | 4,39 | 45 | 2,41 |
125 | 5,51 | 18O | 5,14 | 55 | 2,23 |
15O | 6,07 | 21O | 5,61 | 70 | 2,14 |
18O | 7,25 | 24O | 5,98 | 90 | 2,28 |
22O | 7,64 | 3OO | 7,04 | 12O | 2,20 |
28O | 8,10 |
Table 6 termination
1 | 2 | 3 | 4 | 5 | 6 |
[CH3OH] | Т=3 ' =7,5∙10-2М [CH3OH | 78 TO ] =0,20 M [cH3OH] =0,30 M | |||
5 | 0,08 | 5 | 0,13 | 10 | 0,71 |
10 | 0,19 | 10 | 0,51 | 15 | 1,08 |
15 | 0,75 | 15 | 1,06 | 20 | 1,54 |
20 | 1,49 | 20 | 1,82 | 25 | 2,71 |
25 | 2,53 | 25 | 2,68 | 30 | 3,13 |
30 | 3,47 | 30 | 3,59 | 35 | 4,29 |
35 | 3,87 | 35 | 4,40 | 40 | 4,52 |
45 | 4,85 | 40 | 5,14 | 45 | 5,19 |
60 | 5,80 | 50 | 6,17 | 50 | 5,71 |
80 | 5,54 | 65 | 7,34 | 55 | 6,39 |
110 | 5,24 | 85 | 8,13 | 65 | 7,41 |
140 | 5,88 | 110 | 8,52 | 80 | 8,37 |
180 | 5,76 | 140 | 8,61 | 100 | 9,12 |
130 | 9,54 | ||||
[CH3OH] | T=378 TO =0,45 M [cH3OH] =0,60 M [cH3OH] =0,90 M | ||||
10 | 0,06 | 20 | 0,11 | 5 | 0,02 |
15 | 0,13 | 25 | 0,27 | 15 | 0,06 |
20 | 0,29 | 30 | 0,51 | 30 | 0,36 |
25 | 0,60 | 35 | 0,81 | 45 | 0,94 |
34 | 1,16 | 40 | 1,19 | 60 | 1,45 |
40 | 1,68 | 45 | 1,47 | 80 | 1,93 |
45 | 2,04 | 55 | 2,09 | 100 | 2,26 |
50 | 2,42 | 65 | 2,88 | 120 | 2,45 |
55 | 2,85 | 100 | 5,00 | 140 | 2,53 |
65 | 3,76 | 125 | 5,69 | ||
80 | 4,79 | 150 | 6,77 | ||
100 | 6,11 | 180 | 7,17 | ||
130 | 7,50 | 220 | 7,64 | ||
160 | 8,11 | ||||
200 | 8,61 | ||||
250 | 8,97 |
More on topic the APPENDIX 2 To influence of concentration of reagents, components of catalytic system and temperatures for the speed gidrokarbometokislirovanija tetrahydrobenzene.:
- the APPENDIX 4 To influence of concentration of reagents, components of catalytic system and temperatures for the speed gidrokarbometokislirovanija oktena-1
- results of kinetic experiments on research of influence of reagents, components of catalytic system and temperatures for the speed gidrokarbometoksilirovanija tetrahydrobenzene
- 4.1. Results of experiments on research of influence of concentration of reagents and components of catalytic system for the speed and selectivity gidrokarbometoksilirovanija oktena-1
- Influence of concentration of cations Fe 3 + for speed of dissolution of nickelous sulphide
- Influence of concentration of cations Cu 2 + for speed of dissolution of nickelous sulphide
- 3.2.1 Influence of concentration of peroxide compound of hydrogen and rn for speed of dissolution
- 5.2.2 Analysis of influence of reagents-modifiers on a surface crushed kaolinita
- Influence of a structure of double electric bed on catalytic currents of systems «nickel (II), cobalt (II) - eriochrome black T».
- the APPENDIX 1 Results of chromatographic research of reactionary weight in experiences on gidrokarbometoksilirovaniju tetrahydrobenzene and oktena-1
- the APPENDIX 3 To comparison of some experimental and settlement kinetic curves of accumulation of an aether in time in reaction gidrokarbometoksilirovanija tetrahydrobenzene
- 2.4 Choice of formulas of reagents and laboratory researches of efficiency of influence on productive layers
- CHAPTER 4. INFLUENCE OF CATIONS Fe 3 + AND Cu 2 + FOR SPEED OF DISSOLUTION OF NICKELOUS SULPHIDE (II) IN HYDROGEN NITRATE
- Influence of strength of acid on speed of dissolution
- modern representations about the mechanism of reactions gidrokarbalkoksilirovanija and influence of various factors on their speed and selectivity.
- catalytic systems gidrokarbalkoksilirovanija unsaturated compounds. Approaches in a choice of effective catalytic systems
- Influence of redox potential of a solution and strength of acid for speed of dissolution
- CHAPTER 3. KINETICS OF REACTION gidrokarbometoksilirovanija OF TETRAHYDROBENZENE AT CATALYSIS BY SYSTEM PD (PPh3) 2CL2 - PPH3 - P-TOLUOLSULFOKISLOTA